Ni/C COMPOSITE PREPARATION AND INVESTIGATION OF THE CHARACTERISTICS OF ITS FORMATION ON POROUS CARBON SUPPORT
Abstract
The paper deals with the preparation of nanostructured metal-carbon composite metal nanoparticles by reduction of the iron subgroup (nickel), supported on a mesoporous carbon having a known pore size distribution. It is shown that the formation of metal on the carbon support in the reduction of nickel chloride with hydrazine in an alkaline environment is through the formation of intermediate nickel hydroxide. A method of nickel-carbon composites preparation by reduction of metal nanoparticles on the surface of the carbon support was developped.
About the Authors
A. N. Voropay
Institute of Coal Chemistry and Material Science of the Siberian Branch of the RAS
Russian Federation
Aleksander N. Voropay – post-graduate student
Russian Federation
Aleksander N. Voropay – post-graduate student
R. P. Kolmykov
Kemerovo State University
Russian Federation
Roman P. Kolmykov – Candidate of Chemistry, Head of the Laboratory at the Department of Chemistry of Solids
Russian Federation
Roman P. Kolmykov – Candidate of Chemistry, Head of the Laboratory at the Department of Chemistry of Solids
T. S. Manina
Institute of Coal Chemistry and Material Science of the Siberian Branch of the RAS
Russian Federation
Tatiana S. Manina – post-graduate student
Russian Federation
Tatiana S. Manina – post-graduate student
Ch. N. Barnakov
Institute of Coal Chemistry and Material Science of the Siberian Branch of the RAS
Russian Federation
Chingiz N. Barnakov – Doctor of Chemistry, Head of the Laboratory of High Temperature Processes for Carbon Materials and Coal
Russian Federation
Chingiz N. Barnakov – Doctor of Chemistry, Head of the Laboratory of High Temperature Processes for Carbon Materials and Coal
A. V. Ivanov
Kemerovo State University
Russian Federation
Aleksey V. Ivanov – Leading Engineer at the Department of Chemistry of Solids
Russian Federation
Aleksey V. Ivanov – Leading Engineer at the Department of Chemistry of Solids
A. V. Samarov
Kemerovo State University
Russian Federation
Aleksander V. Samarov – Candidate of Chemistry
Russian Federation
Aleksander V. Samarov – Candidate of Chemistry
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Review
For citations:
Voropay A.N., Kolmykov R.P., Manina T.S., Barnakov Ch.N., Ivanov A.V., Samarov A.V. Ni/C COMPOSITE PREPARATION AND INVESTIGATION OF THE CHARACTERISTICS OF ITS FORMATION ON POROUS CARBON SUPPORT. SibScript. 2013;(3-3):66-69. (In Russ.)
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