ABOUT THE MECHANISM FOR N2O FORMATION IN CATALYZED REACTION BETWEEN HYDROXYLAMMONIUM AND NITRITE IN WATER, ETHYLENE GLYCOL AND DIOXANE
Abstract
The gaseous product of the reaction between hydroxylammonium and nitrite in ethylene glycol, dioxane and ethylene glycol-dioxane mixture was identified as N2O. It was shown that this reaction is catalyzed by boron acid and copper ions. The mechanism for N2O formation and the influence of copper ions on it in water and organic solvents is discussed. The obtained results allow optimizing the conditions of obtaining N2O from hydroxylammonium salts and increasing its yield.
About the Authors
A. S. Bashmakov
Kemerovo State Medical Academy
Russian Federation
Alexander S. Bashmakov – Candidate of Physics and Mathematics, Assistant Professor at the Department of Physical, Colloidal, Analytical and Organic Chemistry
Russian Federation
Alexander S. Bashmakov – Candidate of Physics and Mathematics, Assistant Professor at the Department of Physical, Colloidal, Analytical and Organic Chemistry
E. P. Dyagileva
Kemerovo State Medical Academy
Russian Federation
Elena P. Dyagileva – Candidate of Chemistry, Assistant Professor at the Department of Physical, Colloidal, Analytical and Organic Chemistry
Russian Federation
Elena P. Dyagileva – Candidate of Chemistry, Assistant Professor at the Department of Physical, Colloidal, Analytical and Organic Chemistry
D. A. Kurgachev
Kemerovo State Medical Academy
Russian Federation
Dmitriy A. Kurgachev – Intern at the Department Pharmaceutical Chemistry
Russian Federation
Dmitriy A. Kurgachev – Intern at the Department Pharmaceutical Chemistry
E. V. Leonteva
Kemerovo State Medical Academy
Russian Federation
Elena V. Leonteva – Candidate of Chemistry, Assistant Professor at the Department of Physical, Colloidal, Analytical and Organic Chemistry
Russian Federation
Elena V. Leonteva – Candidate of Chemistry, Assistant Professor at the Department of Physical, Colloidal, Analytical and Organic Chemistry
References
1. Audrieth L. F. Parallelism in the decomposition of ammonium, hydrazine, and hydroxylammonium nitrites. Hyponitrous acid as a hydroxylamino-nitrous acid // J. Phys. Chem. 1930. V. 34. № 3. P. 538 – 542.
2. Bourke G. C. M., Stedman G. Mechanism of the acid catalysed pathway for the nitrosation of hydroxylamine // J. Chem. Soc. 1992. P. 161 – 162.
3. Hughes M. N., Stedman G. Kinetics and mechanism of the reaction between nitrous acid and hydroxylamine. Part I // J. Chem. Soc. 1963. P. 2824 – 2830.
4. Morgan T. D. B., Stedman G., Hughes M. N. Kinetics and mechanism of the reaction between nitrous acid and hydroxylamine. Part II. The alkyl hydroxylamines // J. Chem. Soc. (B). 1968. P. 344 – 349.
5. Hussian M. A., Stedman G., Hughes M. N. Kinetics and mechanism of the reaction between nitrous acid and hydroxylamine. Part III. The formation of hyponitrous acid // J. Chem. Soc. (B). 1968. P. 597 – 603.
6. Уильямс У. Дж. Определение анионов. М.: Химия, 1982. 148 с.
7. Шарло Г. Методы аналитической химии. Количественный анализ неорганических веществ. М.: Химия, 1965. 976 с.
8. Накомото К. ИК спектры и спектры КР неорганических и координационных соединений / пер. с англ. М.: Мир, 1991. 536 с.
9. Lawrence W. G., Apkarian V. A. Infrared studies in free standing crystals: N2O-doped Xe and Ar // J. Phys. Chem. 1992. V. 97. № 4. P. 2224 – 2228.
10. Polydoropoulos C. N., Pipinis M. Kinetics of the decomposition of hyponitrous acid: a homogenious zeroth order reaction // Zeitschrift fur Physikalische Chemie Neue Folge. 1964. Bd. 40. S. 322 – 333.
11. Справочник по растворимости / под ред. В. В. Кафарова. М.: Академия наук СССР, 1961. Т. 1. С. 916 – 920.
12. Anderson J. H. The copper-catalysed oxidation of hydroxylamine // Analyst. 1964. V. 89. P. 357 – 362.
13. Леонтьев А. В., Фомичева О. А., Проскурнина М. В., Зефиров Н. С. Современная химия оксида азота (I) // Успехи химии. 2001 № 70(2). С. 107 – 121.
14. Webb H. W., M. Sc. (B’ham) Absorption of nitrous gases. London: Edward Arnold and co, 1923. P. 372.
Review
For citations:
Bashmakov A.S., Dyagileva E.P., Kurgachev D.A., Leonteva E.V. ABOUT THE MECHANISM FOR N2O FORMATION IN CATALYZED REACTION BETWEEN HYDROXYLAMMONIUM AND NITRITE IN WATER, ETHYLENE GLYCOL AND DIOXANE. SibScript. 2015;(4-3):228-232. (In Russ.)
Views:
422
Email this article 