CHEMICAL ABILITY OF SILVER AZIDE CRYSTALS DOPED BY IONS OF IRON AND LEAD
Abstract
The paper discusses the basic laws of the slow process of decomposition under the action of magnetic, contact electric fields and UV-irradiation in threadlike crystals of silver azide with additionally introduced impurities of iron and lead. The quantitative content of the introduced impurity was determined by means of atomic emission spectroscopy (atomic emission spectrometer with individually-coupled plasma iCAP 6500). Quantitative analysis of the decomposition products was performed with volumetric methods. The experimental results on the influence of impurities on the initiation of the decomposition reaction and the topography of the products of silver azide crystals decomposition were obtained. The authors propose a method of controlling the chemical ability of silver azide crystals with additional introduction of impurities of iron and lead having an effective influence on the nature of the reaction of solid-phase decomposition. The practical significance of the work is determined by the possibility of using experimental results for targeted control of stability and reactivity of silver azide, as well as explosive materials made on its basis.
About the Authors
L. V. Kuz’mina
Kemerovo State University
Russian Federation
Larisa V. Kuz’mina – Doctor of Physics and Mathematics, Professor at the Department of Chemistry of Solids
Russian Federation
Larisa V. Kuz’mina – Doctor of Physics and Mathematics, Professor at the Department of Chemistry of Solids
E. G. Gazenaur
Kemerovo State University
Russian Federation
Ekaterina G. Gazenaur – Candidate of Physics and Mathematics, Assistant Professor at the Department of Chemistry of Solids
Russian Federation
Ekaterina G. Gazenaur – Candidate of Physics and Mathematics, Assistant Professor at the Department of Chemistry of Solids
E. V. Sugatov
Kemerovo State University
Russian Federation
Egor V. Sugatov – post-graduate student at the Department of Chemistry of Solids
Russian Federation
Egor V. Sugatov – post-graduate student at the Department of Chemistry of Solids
V. I. Krasheninin
Kemerovo State University
Russian Federation
Viktor I. Krasheninin – Doctor of Physics and Mathematics, Professor at the Department of Chemistry of Solids
Russian Federation
Viktor I. Krasheninin – Doctor of Physics and Mathematics, Professor at the Department of Chemistry of Solids
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Review
For citations:
Kuz’mina L.V., Gazenaur E.G., Sugatov E.V., Krasheninin V.I. CHEMICAL ABILITY OF SILVER AZIDE CRYSTALS DOPED BY IONS OF IRON AND LEAD. SibScript. 2015;(1-1):34-38. (In Russ.)
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